The reaction mechanism and selectivity of acetylene hydrogenation over Ni–Ga intermetallic compound catalysts: a density functional theory study-Reference-Cited by-同舟云学术

The reaction mechanism and selectivity of acetylene hydrogenation over Ni–Ga intermetallic compound catalysts: a density functional theory study

Published:2018 Issue:12 Volume:47 Page:4198-4208
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rao De-Ming¹²³⁴,Zhang Shi-Tong¹²³⁴,Li Chang-Ming¹²³⁴,Chen Yu-Di⁵⁶⁴,Pu Min¹²³⁴^ORCID,Yan Hong¹²³⁴^ORCID,Wei Min¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering

2. Beijing University of Chemical Technology

3. Beijing 100029

4. China

5. Beijing Centre for Physical & Chemical Analysis

6. Beijing 100089

Abstract

A Ga-rich NiGa(111) surface significantly reduces the adsorption strength of acetylene and ethylene, and shows high selectivity to ethylene for acetylene semihydrogenation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04726F

Reference83 articles.

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3. Pd catalyst promoted by two metal oxides with different reducibilities: Properties and performance in the selective hydrogenation of acetylene

4. A high performance multi-walled carbon nanotube-supported palladium catalyst in selective hydrogenation of acetylene-ethylene mixtures

5. On the Role of Surface Modifications of Palladium Catalysts in the Selective Hydrogenation of Acetylene

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