An unprecedented up-field shift in the 13C NMR spectrum of the carboxyl carbons of the lantern-type dinuclear complex TBA[Ru2(O2CCH3)4Cl2] (TBA+ = tetra(n-butyl)ammonium cation)

Author:

Hiraoka Yuya12345,Ikeue Takahisa12345,Sakiyama Hiroshi67895,Guégan Frédéric1011121314,Luneau Dominique1011121314,Gillon Béatrice1516171814,Hiromitsu Ichiro192345,Yoshioka Daisuke202122235,Mikuriya Masahiro202122235,Kataoka Yusuke12345,Handa Makoto12345

Affiliation:

1. Department of Chemistry

2. Interdisciplinary Graduate School of Science and Engineering

3. Shimane University

4. Matsue 690-8504

5. Japan

6. Department of Material and Biological Chemistry

7. Faculty of Science

8. Yamagata University

9. Yamagata 990-8560

10. Laboratoire des Multimatériaux et Interfaces (UMR 5615)

11. Université Claude Bernard Lyon 1

12. Campus de La Doua

13. 69622 Villeurbanne Cedex

14. France

15. Laboratoire Léon Brillouin CEA/CNRS

16. UMR0012

17. Centre d'Etudes de Saclay

18. Gif sur Yvette

19. Department of Physics and Materials Science

20. Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices

21. School of Science and Technology

22. Kwansei Gakuin University

23. Sanda 669-1337

Abstract

A remarkable up-field shift was found for the carboxyl carbons of TBA[Ru2(O2CCH3)4Cl2] in the 13C NMR spectrum.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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