Methanol oxidative dehydrogenation and dehydration on carbon nanotubes: active sites and basic reaction kinetics

Author:

Yan Pengqiang12345,Zhang Xuefei12345,Herold Felix6789,Li Fan12345,Dai Xueya12345,Cao Tianlong12345,Etzold Bastian J. M.6789,Qi Wei12345ORCID

Affiliation:

1. Shenyang National Laboratory for Materials Science

2. Institute of Metal Research

3. Chinese Academy of Sciences

4. Shenyang

5. P. R. China

6. Ernst-Berl-Institut für Technische und Makromolekulare Chemie

7. Technische Universität Darmstadt

8. Darmstadt

9. Germany

Abstract

In situ active site titration, carbonyl group containing model catalysts, and kinetic analysis have been applied to reveal the nature of oxidized carbon nanotubes catalyzed methanol dehydration and oxidative dehydrogenation reactions.

Funder

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Deutsche Forschungsgemeinschaft

National Natural Science Foundation of China

Deutsche Bundesstiftung Umwelt

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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