In situ transformation of a tridentate to a tetradentate unsymmetric Schiff base ligand via deaminative coupling in Ni(ii) complexes: crystal structures, magnetic properties and catecholase activity study-Reference-Cited by-同舟云学术

In situ transformation of a tridentate to a tetradentate unsymmetric Schiff base ligand via deaminative coupling in Ni(ii) complexes: crystal structures, magnetic properties and catecholase activity study

Published:2020 Issue:1 Volume:7 Page:247-259
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Mondal Monotosh¹²³⁴⁵,Ghosh Soumavo¹²³⁴⁵^ORCID,Maity Souvik¹²³⁴⁵,Giri Sanjib¹⁶⁷⁵^ORCID,Ghosh Ashutosh¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata-700 009

5. India

6. Sri Ramkrishna Sarada Vidya Mahapitha

7. Kamarpukur

Abstract

An N₂O donor reduced Schiff base in presence of Ni(ClO₄)₂·6H₂O and SCN⁻ transforms into N₂O₂ donor ligand via deaminative coupling. Metal complexes 1 and 3 exhibit catecholase like activity and antiferromagnetic coupling between the Ni(ii) ions.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/C9QI00975B

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