Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO2 reduction in water-Reference-Cited by-同舟云学术

Covalent grafting of molecular photosensitizer and catalyst on MOF-808: effect of pore confinement toward visible light-driven CO2 reduction in water

Published:2021 Issue:4 Volume:14 Page:2429-2440
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Karmakar Sanchita¹²³⁴⁵^ORCID,Barman Soumitra¹²³⁴⁵^ORCID,Rahimi Faruk Ahamed¹²³⁴⁵^ORCID,Maji Tapas Kumar¹²³⁴⁵^ORCID

Affiliation:

1. Molecular Materials Laboratory

2. Chemistry and Physics of Materials Unit

3. School of Advanced Materials (SAMat)

4. Jawaharlal Nehru Centre for Advanced Scientific Research

5. Bangalore-560064

Abstract

We have fabricated Zr-MBA-Ru/Re-MOFvia post-synthetic modification of MOF-808. The integrated catalyst assembly was used to mimic natural photosynthesis for sunlight-driven CO₂ reduction to produce CO in aqueous medium without external sacrificial electron donor.

Funder

Council of Scientific and Industrial Research, India

Jawaharlal Nehru Centre for Advanced Scientific Research

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/EE/D0EE03643A

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1. Toward more efficient photochemical CO2 reduction: Use of scCO2 or photogenerated hydrides