Strong Brønsted acid promoted asymmetric hydrogenation of isoquinolines and quinolines catalyzed by a Rh–thiourea chiral phosphine complex via anion binding-Reference-Cited by-同舟云学术

Strong Brønsted acid promoted asymmetric hydrogenation of isoquinolines and quinolines catalyzed by a Rh–thiourea chiral phosphine complex via anion binding

Published:2016 Issue:5 Volume:7 Page:3047-3051
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wen Jialin¹²³⁴,Tan Renchang¹²³⁴,Liu Shaodong¹²³⁴,Zhao Qingyang⁵⁶⁷⁸,Zhang Xumu¹²³⁴

Affiliation:

1. Department of Chemistry & Chemical Biology

2. Rutgers, The State University of New Jersey

3. Piscataway

4. USA

5. College of Chemistry & Materials Science

6. Northwest University

7. Xi'an

8. China

Abstract

Catalyzed by a Rh/bisphosphine–thiourea (L1) complex, isoquinolines and quinolines are hydrogenated with high conversions and high enantioselectivities.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04712A

Reference36 articles.

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4. Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilizing non-covalent interactions

5. Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas

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