Probing the microsolvation of a quaternary ion complex: gas phase vibrational spectroscopy of (NaSO4−)2(H2O)n=0

Probing the microsolvation of a quaternary ion complex: gas phase vibrational spectroscopy of (NaSO4−)2(H2O)n=0–6, 8

Published:2016 Issue:1 Volume:18 Page:267-277
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wende Torsten¹²,Heine Nadja¹²,Yacovitch Tara I.³⁴⁵,Asmis Knut R.¹²⁶⁷⁸,Neumark Daniel M.³⁴⁵⁹¹⁰,Jiang Ling¹²¹¹¹²¹³

Affiliation:

1. Fritz-Haber-Institut der Max-Planck-Gesellschaft

2. Germany

3. Department of Chemistry

4. University of California, Berkeley

5. USA

6. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie

7. Universität Leipzig

8. D-04103 Leipzig

9. Chemical Sciences Division

10. Lawrence Berkeley National Laboratory

11. State Key Laboratory of Molecular Reaction Dynamics

12. Collaborative Innovation Center of Chemistry for Energy and Materials

13. Dalian Institute of Chemical Physics

Abstract

We report infrared multiple photon dissociation spectra of cryogenically-cooled (NaSO₄⁻)₂(H₂O)_n dianions (n = 0–6, 8) in the fingerprint spectral region, which provide evidence for a remarkable stability of the quaternary ion complex upon microhydration.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP05762K

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