Development of sterically hindered siloxide-functionalized polyoxotungstates for the complexation of 5d-metals-Reference-Cited by-同舟云学术

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Development of sterically hindered siloxide-functionalized polyoxotungstates for the complexation of 5d-metals

Published:2021 Issue:12 Volume:50 Page:4300-4310
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Auvray Thomas¹²³⁴^ORCID,Nachtigall Olaf¹²³⁴^ORCID,Brennessel William W.¹²³⁴^ORCID,Jones William D.¹²³⁴^ORCID,Matson Ellen M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Rochester

3. Rochester

4. USA

Abstract

Organosilyl-functionalized trivacant Keggin polyoxotungstates [PW₉O₃₄(RSiOH)₃]³⁻ and their Hf alkoxide complexes have been prepared and characterized to study the influence of the varied steric hindrance from aryl and aliphatic silanol substituents.

Funder

Basic Energy Sciences

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00256B

Reference52 articles.

1. Molecular Metal Catalysts on Supports: Organometallic Chemistry Meets Surface Science

2. Surface-bound metal hydrocarbyls. Organometallic connections between heterogeneous and homogeneous catalysis

3. Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica

4. Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities

5. Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes

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