A polymer rigidity probe based on ultralong organic room temperature phosphorescence of a new skeleton benzo[4,5]imidazo[1,2-a]pyridine

Author:

Ma Jiaxin1,Bai Jingjuan1,Han Lin1,Zhang Xingda1,Liu Yiran1,Bu Lijuan2ORCID,Li Zewei3,Chen Mingxing3,Ma Zhimin3,Ma Zhiyong1ORCID

Affiliation:

1. Beijing Advanced Innovation Center for Soft Matter Science and Engineering, State Key Laboratory of Organic–Inorganic Composites, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

2. Chinese PLA Center for Disease Control and Prevention, Beijing 100071, China

3. College of Engineering, Peking University, Beijing 100871, China

Abstract

We report a new backbone, BNPy. Copolymerizing MA and AA with BNPy derivatives extended UORTP to over 10 s. For BNPy-1, the τp is closely related to the trend of matrix Tg. Thus, BNPy-1 can be used as an efficient polymer rigidity (or Tg) probe.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Beijing Municipal Natural Science Foundation

Beijing University of Chemical Technology

Publisher

Royal Society of Chemistry (RSC)

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