Distinct modes of Si–H binding to Rh in complexes of a phosphine-diarylamido-silane (SiNP) pincer ligand-Reference-Cited by-同舟云学术

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Distinct modes of Si–H binding to Rh in complexes of a phosphine-diarylamido-silane (SiNP) pincer ligand

Published:2022 Issue:37 Volume:51 Page:14150-14155
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rain Talosig A.¹,Cosio Mario N.²,Morse Benjamin¹,Nguyen Vinh T.²^ORCID,Kosanovich Alex J.²,Pell Christopher J.²,Li Chun¹,Bhuvanesh Nattamai²,Zhou Jia³^ORCID,Larsen Anna S.¹,Ozerov Oleg. V.²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Ithaca College, Ithaca New York, 14850, USA

2. Department of Chemistry, Texas A&M University, TAMU – 3255, College Station, TX 77842, USA

3. State Key Laboratory of Urban Water Resource and Environment, School of Science, Harbin Institute of Technology, Shenzhen 518055, China

Abstract

Two distinct Si-H binding modes were observed upon complexation of a silane-amido-phosphine SiNP pincer ligand with monovalent Rh.

Funder

State Key Laboratory of Urban Water Resource and Environment

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02175G

Reference32 articles.

1. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

2. Recent Advances in Nonclassical Interligand Si…H Interactions

3. NMR: A good tool to ascertain σ-silane or σ-borane formulations?

4. Hydrosilylation reaction of olefins: recent advances and perspectives

5. Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

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