A rare example of nickel(ii) chains based on a heteroscorpionate-like ligand with quadruple imidazolyl interactions
Author:
Affiliation:
1. Instituto de Ciencia Molecular (ICMol)
2. Parque Científico
3. Universidad de Valencia
4. 46980 Paterna, Spain
5. Departament de Química Inorgànica
6. Universitat de València
7. 46100 Burjassot, Spain
8. Departament de Química Orgànica
Abstract
The first Ni(ii) complex with 2-di1H-2-imidazolylmethylmalonate (DIMMAL) presents an original quadruple imidazolyl embrace (QIE) and weak antiferromagnetic interactions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01099J
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1. Cooperative H-bonds, π⋯π and anion⋯π interactions as driving forces in the construction of novel Cu(II) bis(imidazol-2-yl) supramolecular 3D frameworks;Polyhedron;2019-10
2. New dinuclear copper complexes incorporating bis(imidazolyl) based ligands and bidentate–monodentate oxalate bridges. Crystal structure and magnetic properties of [Cu2(BIM)2(C2O4)2]·4H2O and [Cu2(BIK)2(C2O4)2] (BIM=bis(2-imidazolyl)methane), BIK=bis(2-imidazolyl)ketone). Exploring magneto-structural correlations;Polyhedron;2016-07
3. Bis(pyrazol‐1‐yl)(pyridin‐x‐yl)methane Ligands – Mono‐ or Ditopic Ligands in Complexes and Supramolecular Frameworks;European Journal of Inorganic Chemistry;2016-02
4. Formation of Mono‐, Di‐ and Trinuclear Species in the Self‐Assembly of Bis(pyrazolyl)(pyridin‐3‐yl)methane Ligands and Metals with Different Coordination Geometries;European Journal of Inorganic Chemistry;2015-11-30
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