Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride-Reference-Cited by-同舟云学术

Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride

Published:2014 Issue:16 Volume:43 Page:6006-6011
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Tan Gengwen¹²³,Wang Wenyuan¹²³⁴⁵,Blom Burgert¹²³,Driess Matthias¹²³

Affiliation:

1. Technische Universität Berlin

2. Department of Chemistry: Metalorganics and Inorganic Materials

3. 10623 Berlin, Germany

4. College of Chemistry & Materials Science

5. Northwest University

Abstract

The mechanism of CO₂ reduction to methanol mediated by germylene hydrides is elucidated based on the model reaction of LAlH₂ with LGeOCH(O) (L = CH(MeCNAr)₂, Ar = 2,6-iPr₂C₆H₃).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53321B

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