Experimental and theoretical elucidation of SPAAC kinetics for strained alkyne-containing cycloparaphenylenes

Author:

Fehr Julia M.1ORCID,Myrthil Nathalie2,Garrison Anna L.1,Price Tavis W.1ORCID,Lopez Steven A.2ORCID,Jasti Ramesh1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon, Eugene, Oregon 97403, USA

2. Department of Chemistry and Chemical Biology, Northeastern University, Boston, Massachusetts 02115, USA

Abstract

Strained alkyne-containing cycloparaphenylenes unite curved carbon nanomaterials with tunable reactivity via physical organic chemistry. Herein we describe the rational design and synthesis of new derivatives with heightened SPAAC reactivity.

Funder

Massachusetts Life Sciences Center

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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