Dual copper- and photoredox-catalysed C(sp2)–C(sp3) coupling-Reference-Cited by-同舟云学术

Dual copper- and photoredox-catalysed C(sp2)–C(sp3) coupling

Published:2019 Issue:29 Volume:55 Page:4238-4241
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

McLean Euan B.¹²³⁴⁵,Gauchot Vincent¹²³⁴⁵,Brunen Sebastian¹²³⁴⁵,Burns David J.⁶⁷⁸⁵,Lee Ai-Lan¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Chemical Sciences

2. School of Engineering and Physical Sciences

3. Heriot-Watt University

4. Edinburgh EH14 4AS

5. UK

6. Syngenta

7. Jealott's Hill International Research Centre

8. Berkshire RG42 6EY

Abstract

The use of copper catalysis with visible light photoredox catalysis in a cooperative fashion has recently emerged as a versatile means of developing new C–C bond forming reactions. In this work, dual copper and photoredox catalysis is exploited to effect C(sp²)–C(sp³) cross-couplings between aryl boronic acids and benzyl bromides.

Funder

Leverhulme Trust

Engineering and Physical Sciences Research Council

Heriot-Watt University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01718F

Reference38 articles.

1. Cooperative photoredox catalysis

2. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

3. Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling

4. Dual Catalysis Strategies in Photochemical Synthesis

5. Combining Photoredox and Metal Catalysis

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