Bipyridine complexes of E3+(E = P, As, Sb, Bi): strong Lewis acids, sources of E(OTf)3and synthons for EIand EVcations-Reference-Cited by-同舟云学术

Bipyridine complexes of E3+(E = P, As, Sb, Bi): strong Lewis acids, sources of E(OTf)3and synthons for EIand EVcations

Published:2015 Issue:11 Volume:6 Page:6545-6555
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chitnis Saurabh S.¹²³⁴,Robertson Alasdair P. M.¹²³⁴,Burford Neil¹²³⁴,Patrick Brian O.¹⁵⁶⁴,McDonald Robert¹⁷⁸⁴,Ferguson Michael J.¹⁷⁸⁴

Affiliation:

1. Department of Chemistry

2. University of Victoria

3. Victoria

4. Canada

5. University of British Columbia

6. Vancouver

7. University of Alberta

8. Edmonton

Abstract

Triflate salts of trications [(bipy)₂E]³⁺([6E][OTf]₃) and [(tbbipy)₂E]³⁺([6′E][OTf]₃) (bipy = 2,2′-bipyridine, tbbipy = 4,4′-di-^tbutyl-2,2′-bipyridine; E = P, As, Sb, Bi) have been synthesized and comprehensively characterized.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02423D

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