Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers-Reference-Cited by-同舟云学术

Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

Published:2015 Issue:18 Volume:51 Page:3878-3881
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Villalba Franco José Manuel¹²³,Sasamori Takahiro⁴⁵⁶⁷,Schnakenburg Gregor¹²³,Espinosa Ferao Arturo⁸⁹¹⁰¹¹¹²,Streubel Rainer¹²³

Affiliation:

1. Institut für Anorganische Chemie der Reinischen Friedrich-Wilhelms-Universität Bonn

2. 53121 Bonn

3. Germany

4. Institut for Chemical Research

5. Kyoto University

6. Gokasho Uji

7. Japan

8. Departamento de Química Orgánica

9. Universidad de Murcia

10. Campus de Espinardo

11. 30100 Murcia

12. Spain

Abstract

Reaction of a Li/Cl phosphinidenoid complex with carbodiimides yielded novel 3-imino-azaphosphiridine complexes, which was converted to the first stable valence isomer of an oxaphosphirane complex.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC10266E

Reference40 articles.

1. Aziridine Imines

2. Synthesis of iminoaziridines from carbodiimides and diazoesters : A new example of transition metal salt catalysed reactions of carbenes

3. Photoextrusion von molekularem Stickstoff aus 5‐Alkyliden‐4,5‐dihydro‐1 H ‐tetrazolen mit Vinyl‐ oder Phenyl‐Substituenten. ( E )‐Aziridinimine und neuartige Produkte

4. A Novel Route to Racemic and Nonracemic Products of the Ugi Reaction: Synthesis of Ugi′s Labile α-Adducts from Iminoaziridines and Carboxylic Acids, and their Transformations

5. Photoextrusion of Molecular Nitrogen from Annulated 5-Alkylidene-4,5-dihydro-1H-tetrazoles: Annulated Iminoaziridines and the First Triplet Diazatrimethylenemethane

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