One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

Author:

Duchemin Coralie1234,Cramer Nicolai1234ORCID

Affiliation:

1. Laboratory of Asymmetric Catalysis and Synthesis

2. EPFL SB ISIC LCSA

3. CH-1015 Lausanne

4. Switzerland

Abstract

A gold(i)trifluoroacetate complex promotes direct additions of N-hydroxyimides to a wide variety of terminal alkynes yielding synthetically valuable N-enoxyimides.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference68 articles.

1. Y. Ashani and I.Silman , in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids, Part 1 , ed. Z. Rappoport and J. F. Liebman , Wiley , Chichester , 2009 , pp. 609–651

2. N–O linkage in carbohydrates and glycoconjugates

3. Synthetic approaches to the 2010–2014 new agrochemicals

4. M. Manuela , A.Pereira and P. P.Santos , in The Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids, Part 1 , ed. Z. Rappoport and J. F. Liebman , Wiley , Chichester , 2009 , pp. 343–498

5. Rearrangement of N-Oxyenamines and Related Reactions

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