Vibrational circular dichroism and single crystal X-Ray diffraction analyses of [Ir(bzq)2(phen)]+ (bzq = benzo[h]quinoline; phen = 1,10-phenanthroline): absolute configuration and role of CH–π interaction in molecular packing-Reference-Cited by-同舟云学术

Vibrational circular dichroism and single crystal X-Ray diffraction analyses of [Ir(bzq)2(phen)]+ (bzq = benzo[h]quinoline; phen = 1,10-phenanthroline): absolute configuration and role of CH–π interaction in molecular packing

Published:2017 Issue:13 Volume:46 Page:4397-4402
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Takimoto Kazuyoshi¹²³⁴⁵,Watanabe Yutaka¹²³⁴⁵,Mori Shigeki⁶³⁴⁵,Sato Hisako¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Engineering

3. Ehime University

4. Matsuyama 790-8577

5. Japan

6. Advanced Research Support Center

Abstract

The absolute configuration of a cationic iridium(iii) complex was determined in solution and solid by vibrational circular dichroism and X-ray diffraction analyses.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00606C

Reference53 articles.

1. Luminescent films for chemo- and biosensing

2. Luminescent Rhenium(I) and Iridium(III) Polypyridine Complexes as Biological Probes, Imaging Reagents, and Photocytotoxic Agents

3. Asymmetric photoredox transition-metal catalysis activated by visible light

4. Synthetically Tailored Excited States: Phosphorescent, Cyclometalated Iridium(III) Complexes and Their Applications

5. Synthesis and Characterization of Facial and Meridional Tris-cyclometalated Iridium(III) Complexes

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