A (TD-)DFT study on photo-NHC catalysis: photoenolization/Diels–Alder reaction of acid fluorides catalyzed by <i>N</i>-heterocyclic carbenes-Reference-Cited by-同舟云学术

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A (TD-)DFT study on photo-NHC catalysis: photoenolization/Diels–Alder reaction of acid fluorides catalyzed by N-heterocyclic carbenes

Published:2023 Issue:15 Volume:14 Page:4027-4037
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mavroskoufis Andreas¹^ORCID,Lohani Manish²,Weber Manuela¹^ORCID,Hopkinson Matthew N.¹³^ORCID,Götze Jan P.²^ORCID

Affiliation:

1. Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195 Berlin, Germany

2. Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, 14195 Berlin, Germany

3. School of Natural and Environmental Sciences, Newcastle University, Bedson Building, Newcastle upon Tyne, NE1 7RU, UK

Abstract

A full, concise reaction pathway for the PEDA catalysis cycle using NHC was identified by experiment and theory.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC04732B

Reference72 articles.

1. Organocatalysis by N-Heterocyclic Carbenes

2. A Continuum of Progress: Applications of N-Hetereocyclic Carbene Catalysis in Total Synthesis

3. Organocatalytic umpolung: N-heterocyclic carbenes and beyond

4. An overview of N-heterocyclic carbenes

5. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

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