Metathesis of a UV imido complex: a route to a terminal UV sulfide-Reference-Cited by-同舟云学术

Metathesis of a UV imido complex: a route to a terminal UV sulfide

Published:2017 Issue:8 Volume:8 Page:5319-5328
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kelly Rory P.¹²³⁴,Falcone Marta¹²³⁴,Lamsfus Carlos Alvarez⁵⁶⁷⁸⁹,Scopelliti Rosario¹²³⁴,Maron Laurent⁵⁶⁷⁸⁹,Meyer Karsten¹⁰¹¹¹²¹³¹⁴,Mazzanti Marinella¹²³⁴^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques

2. Ecole Polytechnique Fédérale de Lausanne (EPFL)

3. 1015 Lausanne

4. Switzerland

5. Université de Toulouse et CNRS INSA

6. UPS

7. CNRS

8. UMR 5215

9. LPCNO

10. Department of Chemistry and Pharmacy

11. Inorganic Chemistry

12. Friedrich-Alexander University Erlangen-Nürnberg

13. 91058 Erlangen

14. Germany

Abstract

The metathesis reaction of a U^V imido complex supported by sterically demanding tris(tert-butoxy)siloxide ligands with CS₂ afforded a terminal U^V thiocarbonate but metathesis with H₂S afforded the first example of a terminal U^V sulfide.

Funder

École Polytechnique Fédérale de Lausanne

Swiss National Science Foundation

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC01111C

Reference86 articles.

1. The Renaissance of Non-Aqueous Uranium Chemistry