Carboberyllation: addition of organoberyllium species to alkenes and alkynes. A comparison with carboboration-Reference-Cited by-同舟云学术

Carboberyllation: addition of organoberyllium species to alkenes and alkynes. A comparison with carboboration

Published:2017 Issue:24 Volume:46 Page:7686-7692
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Field-Theodore Terri E.¹²³⁴⁵,Couchman Shannon A.¹²³⁴⁵,Wilson David J. D.¹²³⁴⁵^ORCID,Dutton Jason L.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Physics

2. La Trobe Institute for Molecular Science

3. La Trobe University

4. Melbourne

5. Australia

Abstract

A theoretical evaluation of the unknown addition of diorganoberyllium to model alkenes and alkynes (carboberyllation) shows the reaction with alkynes should be feasible. In contrast with carboboration a 1,2-regioselectivity is predicted.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01370A

Reference40 articles.

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5. Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

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