A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes
Author:
Affiliation:
1. Laboratory of Asymmetric Catalysis and Synthesis
2. EPFL SB ISIC LCSA
3. CH-1015 Lausanne
4. Switzerland
5. Laboratory for Computational Molecular Design
6. EPFL SB ISIC LCMD
Abstract
Stable pre-ligands and common metal salts provide,viaβ-carbon elimination, access to Cp-metal complexes suitable forin situcatalyst preparation.
Funder
Swiss National Science Foundation
Seventh Framework Programme
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02986A
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2. Rhodium(III)-Catalyzed C–H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate
3. Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes
4. Rhodium-catalysed syn-carboamination of alkenes via a transient directing group
5. Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C–H Activation
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