Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

Author:

Fiore Ambra Maria12,Petrelli Valentina2,Fliedel Christophe3ORCID,Manoury Eric3ORCID,Mastrorilli Piero2ORCID,Poli Rinaldo34ORCID

Affiliation:

1. Dipartimento di Chimica, Università degli studi di Bari “Aldo Moro”, via Orabona, 4, 70125 Bari, Italy

2. DICATECh, Politecnico di Bari, via Orabona, 4, 70125 Bari, Italy

3. CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse, 205 route de Narbonne, F-31077 Toulouse, Cedex 4, France

4. Institut Universitaire de France, 1, rue Descartes, 75231 Paris, France

Abstract

[Rh(COD)(μ-OAc)]2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc)2] and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micelle latexes.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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