Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(<scp>i</scp>) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes-Reference-Cited by-同舟云学术

Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

Published:2023 Issue:35 Volume:52 Page:12534-12542
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fiore Ambra Maria¹²,Petrelli Valentina²,Fliedel Christophe³^ORCID,Manoury Eric³^ORCID,Mastrorilli Piero²^ORCID,Poli Rinaldo³⁴^ORCID

Affiliation:

1. Dipartimento di Chimica, Università degli studi di Bari “Aldo Moro”, via Orabona, 4, 70125 Bari, Italy

2. DICATECh, Politecnico di Bari, via Orabona, 4, 70125 Bari, Italy

3. CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse, 205 route de Narbonne, F-31077 Toulouse, Cedex 4, France

4. Institut Universitaire de France, 1, rue Descartes, 75231 Paris, France

Abstract

[Rh(COD)(μ-OAc)]2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc)2]− and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micelle latexes.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02260A

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4. One-Pot RAFT Synthesis of Triphenylphosphine-Functionalized Amphiphilic Core-Shell Polymers and Application as Catalytic Nanoreactors in Aqueous Biphasic Hydroformylation

5. Coordination Chemistry Inside Polymeric Nanoreactors: Interparticle Metal Exchange and Ionic Compound Vectorization in Phosphine-Functionalized Amphiphilic Polymer Latexes