Charge transfer mediated triplet excited state formation in donor–acceptor–donor BODIPY: Application for recording of holographic structures in photopolymerizable glass

Author:

Mikulchyk Tatsiana1ORCID,Karuthedath Safakath2ORCID,De Castro Catherine S. P.2,Buglak Andrey A.34ORCID,Sheehan Aimee5,Wieder Aaron5,Laquai Frédéric2ORCID,Naydenova Izabela1ORCID,Filatov Mikhail A.5ORCID

Affiliation:

1. Centre for Industrial and Engineering Optics, School of Physics and Clinical and Optometric Sciences, College of Science and Health, Technological University Dublin, City Campus, Grangegorman, Dublin 7, Ireland

2. King Abdullah University of Science and Technology (KAUST), KAUST Solar Center (KSC), Physical Sciences and Engineering Division (PSE), Material Science and Engineering Program (MSE), Thuwal, 23955-6900, Kingdom of Saudi Arabia

3. Faculty of Physics, Saint-Petersburg State University, University Emb. 7-9, 199034, St. Petersburg, Russia

4. Institute of Physics, Kazan Federal University, Kremlevskaya 18, Kazan, 420008, Russia

5. School of Chemical and Pharmaceutical Sciences, Technological University Dublin, City Campus, Grangegorman, Dublin 7, Ireland

Abstract

Novel BODIPY forming triplet excited states via the SOCT-ISC process was used for polymerization of methacrylate monomers inside a hybrid sol–gel material. Holographic recording of diffractive structures with high efficiency was demonstrated.

Funder

King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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