Proximate stochastic chiral symmetry breaking is mechanically tunable: formation of enantiomeric hetero-double-helices and aggregates from racemic oxymethylenehelicene oligomers-Reference-Cited by-同舟云学术

Proximate stochastic chiral symmetry breaking is mechanically tunable: formation of enantiomeric hetero-double-helices and aggregates from racemic oxymethylenehelicene oligomers

Published:2019 Issue:45 Volume:21 Page:25406-25414
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sawato Tsukasa¹²³⁴⁵,Saito Nozomi¹²³⁴⁵,Yamaguchi Masahiko¹²³⁴⁵^ORCID

Affiliation:

1. Department of Organic Chemistry

2. Graduate School of Pharmaceutical Sciences

3. Tohoku University

4. Sendai 980-8578

5. Japan

Abstract

A mixture of oxymethylenehelicene (P)-hexamer and (M)-hexamer in solution exhibited chiral symmetry breaking, which was induced by mechanical stirring, during the formation of enantiomeric hetero-double-helices and their aggregates.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP04299G

Reference48 articles.

1. On spontaneous asymmetric synthesis

2. Chiral Symmetry Breaking in Nonequilibrium Systems

3. Chiral-symmetry-breaking states and their sensitivity in nonequilibrium chemical systems

4. The parity-violating energy differences between the enantiomers of α-amino acids

5. The electroweak origin of biomolecular handedness

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