Disulfide bond photochemistry: the effects of higher excited states and different molecular geometries on disulfide bond cleavage-Reference-Cited by-同舟云学术

Disulfide bond photochemistry: the effects of higher excited states and different molecular geometries on disulfide bond cleavage

Published:2019 Issue:8 Volume:21 Page:4176-4183
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cao Jun¹²³⁴⁵^ORCID,Chen Dong-Chu¹²³⁴

Affiliation:

1. School of Materials Science and Energy Engineering

2. Foshan University, Foshan

3. Guangdong

4. P. R. China

5. Guizhou Provincial Key Laboratory of Computational Nano-material Science

Abstract

We have investigated the light-induced cleavage of disulfide bond using MS-CASPT2 based trajectory simulations and provided insights into the intrinsic excited state properties of disulfide molecules.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06891G

Reference40 articles.

1. Ultraviolet photodissociation study of CH3SCH3 and CH3SSCH3

2. Laser flash photolysis study of bis(1,3-benzoxazol-2-yl) disulfide and bis(1,3-benzothiazol-2-yl) disulfide; reactivities of benzoxazol-2-ylsulfanyl and benzothiazol-2-ylsulfanyl radicals

3. Competition between Geminate Recombination and Solvation of Polar Radicals following Ultrafast Photodissociation of Bis(p-aminophenyl) Disulfide

4. Photodissociation dynamics of dimethyl disulfide

5. UV-Photochemistry of the Disulfide Bond: Evolution of Early Photoproducts from Picosecond X-ray Absorption Spectroscopy at the Sulfur K-Edge

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