Influence of solvent mixture on nucleophilicity parameters: the case of pyrrolidine in methanol

Influence of solvent mixture on nucleophilicity parameters: the case of pyrrolidine in methanol–acetonitrile

Published:2020 Issue:48 Volume:10 Page:28635-28643
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Souissi Salma¹²³⁴⁵^ORCID,Gabsi Wahiba¹²³⁴⁵,Echaieb Abderraouf¹²³⁴⁵,Roger Julien⁶⁷⁸⁹^ORCID,Hierso Jean-Cyrille⁶⁷⁸⁹^ORCID,Fleurat-Lessard Paul⁶⁷⁸⁹^ORCID,Boubaker Taoufik¹²³⁴⁵

Affiliation:

1. Université de Monastir

2. Faculté des Sciences

3. Laboratoire de Chimie Hétérocyclique

4. Produits Naturels et Réactivité (LR11S39)

5. 5019 Monastir

6. Institut de Chimie Moléculaire de l’Université de Bourgogne (UMR-CNRS 6302)

7. Université Bourgogne Franche-Comté (UBFC)

8. 21078 Dijon

9. France

Abstract

Combined experiments and modelling rationalize the large influence of solvent composition on pyrrolidine nucleophilicity.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université de Bourgogne

European Commission

Ministère de l’enseignement supérieur et de la recherche scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA06324J

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