Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate–n-dodecane solvent extraction system-Reference-Cited by-同舟云学术

Structural insights into the multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate–n-dodecane solvent extraction system

Published:2017 Issue:32 Volume:19 Page:21304-21316
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Antonio Mark R.¹²³⁴^ORCID,Ellis Ross J.¹²³⁴,Estes Shanna L.¹²³⁴^ORCID,Bera Mrinal K.¹²³⁴

Affiliation:

1. Chemical Sciences and Engineering Division

2. Argonne National Laboratory

3. Argonne

4. USA

Abstract

Macroscopic phase behaviors in the liquid–liquid extraction are explained by microscopic, reverse micellar fluid structures containing tetranuclear Ce(iv) clusters revealed by use of X-ray spectroscopy and scattering of the light and dense organic phases.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03350H

Reference88 articles.

1. V. V. Fomin , Chemistry of Extraction Processes (Khimiya ekstraktsionnykh protsessov), Israel Program for Scientific Translations, Jerusalem, 1962

2. J. A. Brient , P. J.Wessner and M. N.Doyle, in Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc., 2000

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