Fluorescent nano-sized aggregates of halogen bonded complexes formed using perfluoropropyl iodides: a systematic comparison between two isomeric halogen bond acceptors, aniline and 4-methyl pyridine

Author:

Fan Haiyan1ORCID,Nurtay Lazzat1,Daniyeva Nurgul2,Benassi Enrico3ORCID

Affiliation:

1. Chemistry Department, School of Sciences and Humanities, Nazarbayev University, Astana 010000, Kazakhstan

2. Core Facility, Nazarbayev University, Astana 010000, Kazakhstan

3. Faculty of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russian Federation

Abstract

The halogen bonds formed by the two isomers 4-methyl pyridine and aniline with heptafluoro-1- and heptafluoro-2-propyl iodide were investigated using vibrational (FT-IR and Raman) spectroscopy, SEM, TEM and quantum mechanical calculations.

Funder

Nazarbayev University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference53 articles.

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2. The Merck Index – An Encyclopedia of Chemicals, Drugs, and Biologicals , ed. M. J. O'Neil, Royal Society of Chemistry , Cambridge, UK , 2013 , p. 1374

3. E. F. V.Scriven and R.Murugan , Pyridine and Pyridine Derivatives, Kirk-Othmer Encyclopedia of Chemical Technology , John Wiley & Sons , New York, NY , 2005

4. Excess volumes and excess viscosities of binary mixtures of cyclohexane + picoline

5. Studies of Hydrogen Bonding. Part XXXVI. Dipole Moments of Pyridines, Quinolines and Acridine, and of their Hydrogen-Bonded Complexes with Phenol.

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