One pot tandem dual CC and CO bond reductions in the β-alkylation of secondary alcohols with primary alcohols by ruthenium complexes of amido and picolyl functionalized N-heterocyclic carbenes-Reference-Cited by-同舟云学术

One pot tandem dual CC and CO bond reductions in the β-alkylation of secondary alcohols with primary alcohols by ruthenium complexes of amido and picolyl functionalized N-heterocyclic carbenes

Published:2021 Issue:43 Volume:50 Page:15640-15654
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Prakasham A. P.¹,Ta Sabyasachi¹,Dey Shreyata¹,Ghosh Prasenjit¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India

Abstract

A neutral amido-functionalized ruthenium complex and a cationic picolyl-functionalized ruthenium complex of NHC ligands efficiently catalysed tandem β-alkylation reaction of alcohols, including the synthesis of various bioactive flavan derivatives.

Funder

Indian Institute of Technology Bombay

Science and Engineering Research Board

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02849A

Reference53 articles.

1. Efficient Iridium-Thioether-Dithiolate Catalyst for β-Alkylation of Alcohols and Selective Imine Formation via N-Alkylation Reactions