A practical deca-gram scale ring expansion of (R)-(−)-carvone to (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1-Reference-Cited by-同舟云学术

A practical deca-gram scale ring expansion of (R)-(−)-carvone to (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1

Published:2015 Issue:28 Volume:13 Page:7633-7642
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Alves Leandro de C.¹²³⁴,Desiderá André L.¹²³⁴,de Oliveira Kleber T.¹²³⁴,Newton Sean⁵⁶⁷⁸,Ley Steven V.⁵⁶⁷⁸,Brocksom Timothy J.¹²³⁴

Affiliation:

1. Departamento de Química

2. Universidade Federal de São Carlos

3. São Carlos – SP

4. Brazil

5. Department of Chemistry

6. University of Cambridge

7. Cambridge

8. UK

Abstract

A route to enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1, an intermediate for terpenoids, has been developed and includes a highly chemo- and regioselective Tiffeneau–Demjanov reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00525F

Reference121 articles.

1. The Synthesis of Seven-Membered Rings in Natural Products

2. TOTAL SYNTHESIS OF d,l-LONGIFOLENE

3. Total Synthesis of Longifolene

4. Synthesis of the thapsigargins

Cited by 16 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Advances in the Continuous Flow Synthesis of 3‐ and 4‐Membered Ring Systems;Chemistry – A European Journal;2024-05-02

2. Continuous flow reactions in the preparation of active pharmaceutical ingredients and fine chemicals;Chemical Communications;2024

3. Durchflusschemieansätze angewendet auf die Synthese von gesättigten Heterocyclen;Flow-Chemie für die Synthese von Heterocyclen;2024

4. Corey-Chaykovsky Reaction and Related Processes;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2024

5. An Enantiospecific Synthesis of 5-epi-α-Bulnesene;Molecules;2023-05-05