Experimental and theoretical study of dimer-of-dimers-type tetrarhodium(ii) complexes bridged by 1,4-benzenedicarboxylate linkers
Author:
Affiliation:
1. Department of Chemistry
2. Interdisciplinary Graduate School of Science and Engineering
3. Shimane University
4. Matsue
5. Japan
6. Faculty of Science
7. Kanagawa University
8. Hiratsuka
Abstract
Two dimer-of-dimers-type tetrarhodium complexes, [Rh4(piv)6(BDC)] and [Rh4(piv)6(F4BDC)], in which two paddlewheel-type dirhodium units are linked by dicarboxylate ligands, have been synthesized and characterized.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03293A
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