Experimental and theoretical study of dimer-of-dimers-type tetrarhodium(ii) complexes bridged by 1,4-benzenedicarboxylate linkers

Author:

Kataoka Yusuke12345,Arakawa Kazuki12345,Ueda Hikaru12345,Yano Natsumi12345,Kawamoto Tatsuya16785,Handa Makoto12345ORCID

Affiliation:

1. Department of Chemistry

2. Interdisciplinary Graduate School of Science and Engineering

3. Shimane University

4. Matsue

5. Japan

6. Faculty of Science

7. Kanagawa University

8. Hiratsuka

Abstract

Two dimer-of-dimers-type tetrarhodium complexes, [Rh4(piv)6(BDC)] and [Rh4(piv)6(F4BDC)], in which two paddlewheel-type dirhodium units are linked by dicarboxylate ligands, have been synthesized and characterized.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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