Transition-metal-free C–C σ-bond activation of α-aryl ketones and subsequent Zn-catalyzed intramolecular cyclization: synthesis of tetrasubstituted furans-Reference-Cited by-同舟云学术

Transition-metal-free C–C σ-bond activation of α-aryl ketones and subsequent Zn-catalyzed intramolecular cyclization: synthesis of tetrasubstituted furans

Published:2019 Issue:10 Volume:17 Page:2725-2733
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yuan Yang¹²³^ORCID,Tan Hailu¹²³,Kong Lingkai¹²³,Zheng Zhong¹²³^ORCID,Xu Murong¹²³^ORCID,Huang Jiaqi¹²³,Li Yanzhong¹²³^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes

2. School of Chemistry and Molecular Engineering East China Normal University

3. China

Abstract

Atom-economical synthesis of tetrasubstituted furans from α-aryl ketones and alkynones through base-promoted cleavage of unstrained C–C single bonds of ketones and subsequent Zn-catalyzed cyclization.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00081J

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