Influence of water on the deprotonation and the ionic mechanisms of a Heck alkynylation and its resultant E-factors-Reference-Cited by-同舟云学术

Influence of water on the deprotonation and the ionic mechanisms of a Heck alkynylation and its resultant E-factors

Published:2016 Issue:1 Volume:1 Page:65-72
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Hu Chuntian¹²³⁴,Shaughnessy Kevin H.⁵⁶⁷⁴,Hartman Ryan L.¹²³⁴

Affiliation:

1. Department of Chemical and Biomolecular Engineering

2. New York University

3. Brooklyn

4. USA

5. Department of Chemistry

6. The University of Alabama

7. Tuscaloosa

Abstract

Water influences the catalysis of Heck alkynylation. The hydrophilic ligand concentration also influences the E-factor, and it can induce mass transport limitations.

Funder

Directorate for Biological Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RE/C5RE00034C

Reference50 articles.

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4. Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

5. Heck Reactions in the Presence of P(t-Bu)3: Expanded Scope and Milder Reaction Conditions for the Coupling of Aryl Chlorides

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