Mesoporous Zr-Beta zeolites prepared by a post-synthetic strategy as a robust Lewis acid catalyst for the ring-opening aminolysis of epoxides

Author:

Tang Bo12345,Dai Weili12345,Sun Xiaoming12345,Wu Guangjun12345,Guan Naijia12345,Hunger Michael6789,Li Landong12345

Affiliation:

1. Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education

2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

3. Nankai University

4. Tianjin 300071

5. China

6. Institute of Chemical Technology

7. University of Stuttgart

8. 70550 Stuttgart

9. Germany

Abstract

Mesoporous Zr-Beta exhibits a remarkable catalytic activity and regio-selectivity to β-amino alcohols in epoxide aminolysis. Intra-crystalline mesopores greatly promote the reaction through enhanced mass transfer and suppress the catalytic deactivation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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