Finding a new pathway for acid-induced nitrite reduction reaction: formation of nitric oxide with hydrogen peroxide-Reference-Cited by-同舟云学术

Finding a new pathway for acid-induced nitrite reduction reaction: formation of nitric oxide with hydrogen peroxide

Published:2019 Issue:37 Volume:48 Page:13916-13920
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Puthiyaveetil Yoosaf Mohammed Ajmal¹²³⁴,Ghosh Somnath¹²³⁴,Narayan Yatheesh¹²³⁴,Yadav Munendra¹⁵⁶⁴,Sahoo Subash Chandra¹⁷⁸⁹^ORCID,Kumar Pankaj¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Science Education and Research (IISER)

3. Tirupati 517507

4. India

5. Punjab University

6. Chandigarh

7. University of Texas at El Paso

8. El Paso

9. USA

Abstract

Here, we report a new pathway for nitrite reduction chemistry, formation of cobalt-nitrosyl ({Co^II-NO}⁸) with H₂O₂ in the reaction of a Co^II-nitrito complex with a one-fold acid (H⁺) via the formation of a Co^II-nitrous acid intermediate ({Co^II-ONOH}).

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02834J

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