A double-helical S,C-bridged tetraphenyl-para-phenylenediamine and its persistent radical cation

Author:

Harada Kaho1,Hasegawa Chika2,Matsumoto Taisuke3,Sugishita Hiroki1,Kitamura Chitoshi1,Higashibayashi Shuhei4ORCID,Hasegawa Masashi2ORCID,Suzuki Shuichi5ORCID,Kato Shin-ichiro1ORCID

Affiliation:

1. Department of Materials Science, School of Engineering, The University of Shiga Prefecture, 2500 Hassaka-cho, Hikone, Shiga 522-8533, Japan

2. Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato, Minami-ku, Sagamihara, Kanagawa 252-0373, Japan

3. Institute for Materials Chemistry and Engineering (IMCE), Kyushu University, 6-1 Kasuga-koh-en, Kasuga 816-8580, Japan

4. Faculty of Pharmacy, Keio University, 1-5-30, Shibakoen, Minato-ku, Tokyo 105-8512, Japan

5. Department of Chemistry, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama-cho, Toyonaka, Osaka 560-8531, Japan

Abstract

The title compound has a sufficiently persistent radical cationic state and enough chiral stability for optical resolution.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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