Interligand communication in a metal mediated LL′CT system – a case study
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology
2. Indiana University – Purdue University Indianapolis
3. Indianapolis
4. USA
5. Department of Chemistry and Biochemistry
6. Duquesne University
7. Pittsburgh
Abstract
The interligand communication between non-innocent dithiolene ligands of different oxidation states has been described in a Mo system. The fully reduced ene-dithiolate (Dt2−) acts as a donor moiety to the oxidized dithione (Dt0) in an LL′CT process.
Funder
National Institute of General Medical Sciences
Indiana University-Purdue University Indianapolis
National Institutes of Health
Lilly Endowment
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA04716G
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