Two heads are better than one: improving magnetic relaxation in the dysprosium metallocene upon dimerization by use of an exceptionally weakly-coordinating anion-Reference-Cited by-同舟云学术

Two heads are better than one: improving magnetic relaxation in the dysprosium metallocene upon dimerization by use of an exceptionally weakly-coordinating anion

Published:2020 Issue:44 Volume:56 Page:5937-5940
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Errulat Dylan¹²³⁴,Gabidullin Bulat⁵⁶⁴,Mansikkamäki Akseli⁷⁸⁹¹⁰^ORCID,Murugesu Muralee¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Sciences

2. University of Ottawa

3. Ottawa

4. Canada

5. Canadian Light Source Inc.

6. Saskatoon

7. NMR Research Unit

8. University of Oulu

9. 90014 Oulu

10. Finland

Abstract

Combining two weakly-coordinating anions in the archetypical metallocene results in the first example of [BPh₄]⁻ as a bridging ligand in 4f metals, resulting in improved magnetic relaxation dynamics over its mononuclear counterpart.

Funder

University of Ottawa

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Magnus Ehrnroothin Säätiö

Oulun Yliopisto

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01980A

Reference32 articles.

1. Large Spin-Relaxation Barriers for the Low-Symmetry Organolanthanide Complexes [Cp*2Ln(BPh4)] (Cp*=pentamethylcyclopentadienyl; Ln=Tb, Dy)

2. Slow magnetic relaxation in a neodymium metallocene tetraphenylborate complex

3. Reduction of Dinitrogen with an Yttrium Metallocene Hydride Precursor, [(C5Me5)2YH]2

4. Expanding the LnZ3/Alkali-Metal Reduction System to Organometallic and Heteroleptic Precursors: Formation of Dinitrogen Derivatives of Lanthanum

5. A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

Cited by 22 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. An alkoxyborate-bridging Dy₂ single-molecule magnet with ferromagnetic coupling;Inorganic Chemistry Frontiers;2024

2. Increasing the Symmetry around Lanthanide Ions: The Effect on Single-Ion Magnet Behavior and Electronic Structure;Crystal Growth & Design;2023-12-14

3. AtomAccess: A Predictive Tool for Molecular Design and Its Application to the Targeted Synthesis of Dysprosium Single-Molecule Magnets;Journal of the American Chemical Society;2023-10-05

4. Targeted Synthesis of End-On Dinitrogen-Bridged Lanthanide Metallocenes and Their Reactivity as Divalent Synthons;Journal of the American Chemical Society;2023-09-01

5. Pyrrolyl-Bridged Metallocene Complexes: From Synthesis, Electronic Structure, to Single-Molecule Magnetism;Inorganic Chemistry;2023-08-28