Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels

Author:

Tso Ken Chi-Hang123,Chan Sharon Lai-Fung43567,Huang Jie-Sheng123ORCID,Che Chi-Ming12389

Affiliation:

1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry

2. The University of Hong Kong

3. China

4. The Hong Kong Polytechnic University Shenzhen Research Institute

5. Department of Applied Biology and Chemical Technology

6. The Hong Kong Polytechnic University

7. Kowloon

8. HKU Shenzhen Institute of Research and Innovation

9. Shenzhen 518053

Abstract

This communication reports a ruthenium-thiolate molecular rhomboid (◇)-[Ru(SAr)2(CO)2]8 produced by isomerization of the molecular wheel (○)-[Ru(SAr)2(CO)2]8, along with the use of a (○)-[Ru(SAr)2(CO)2]6 wheel for catalytic aziridination of alkenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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