Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel–Crafts type cyclization-Reference-Cited by-同舟云学术

Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel–Crafts type cyclization

Published:2016 Issue:55 Volume:52 Page:8561-8564
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Dong¹²³⁴⁵,Xu Wen-Dan¹²³⁴⁵,Liu Hao-Miao¹²³⁴⁵,Li Ming-Ming⁶⁷⁸,Yan Yong-Min¹²³⁴⁵,Li Xiao-Nian¹²³⁴⁵,Li Yan¹²³⁴⁵,Cheng Yong-Xian¹²³⁴⁵,Qin Hong-Bo¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Photochemistry and Plant Resources in West China

2. Kunming Institute of Botany

3. Chinese Academy of Sciences

4. Kunming 650201

5. P. R. China

6. Yunnan Baiyao Group Corporation Limited

7. Kunming 650032

8. China

Abstract

Enantioselective total synthesis of (+)-Lingzhiol has been achieved. Tandem semipinacol rearrangement/lactone formation/Friedel–Crafts cyclization/elimination reaction was developed to construct the four-ring core skeleton.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC03764J

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