Hydrothermal synthesis of (Zr,U)SiO4: an efficient pathway to incorporate uranium into zircon

Author:

Estevenon Paul1ORCID,Barral Thomas2ORCID,Avallone Arthur2ORCID,Jeffredo Mateo2ORCID,De La Hos Alexis2ORCID,Strzelecki Andrew345ORCID,Le Goff Xavier2ORCID,Szenknect Stephanie2ORCID,Kvashnina Kristina67ORCID,Moisy Philippe1ORCID,Podor Renaud2ORCID,Guo Xiaofeng345ORCID,Dacheux Nicolas2ORCID

Affiliation:

1. CEA, DES, ISEC, DMRC, Univ Montpellier, Marcoule, France

2. ICSM, Univ Montpellier, CNRS, CEA, ENSCM, Bagnols-sur-Cèze, France

3. Department of Chemistry, Washington State University, Pullman, Washington 99164, USA

4. Alexandra Navrotsky Institute for Experimental Thermodynamics, Washington State University, Pullman, Washington 99164, USA

5. Materials Science and Engineering, Washington State University, Pullman, Washington 99164, USA

6. Helmholtz Zentrum Dresden Rossendorf (HZDR), Institute of Resource Ecology, 01314 Dresden, Germany

7. The Rossendorf Beamline at ESRF–The European Synchrotron, 38043 Grenoble, Cedex 9, France

Abstract

For the first time, conditions allowing the formation of (Zr,U)SiO4 solid solution with uranium content up to 60 mol% have been determined through the hydrothermal synthesis pathway.

Funder

Institut National de Physique Nucléaire et de Physique des Particules

Publisher

Royal Society of Chemistry (RSC)

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