Uncatalyzed conjugate addition of organozinc halides to enones in DME: a combined experimental/computational study on the role of the solvent and the reaction mechanism
Author:
Affiliation:
1. Dipartimento di Chimica e Chimica Industriale
2. Università di Pisa
3. 56124 Pisa
4. Italy
Abstract
The reaction mechanism of a new conjugate addition reaction of organozinc halides to enones is disclosed by a combined experimental/computational study.
Funder
Università di Pisa
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC04820K
Reference36 articles.
1. P. Perlmutter , Conjugate Addition Reactions in Organic Synthesis , Pergamon , 1992
2. Copper-Catalyzed Enantioselective 1,4-Addition to α,β-Unsaturated Aldehydes
3. B. J. Wakefield , Organomagnesium Methods in Organic Synthesis , Elsevier , 1995
4. Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones
5. Regioselective 1,4- and 1,6-Conjugate Additions of Grignard Reagent-Derived Organozinc(II)ates to Polyconjugated Esters
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