Simple generation of a dirhodium μ-carbido complex via thiocarbonyl reduction
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra
4. Australia
Abstract
The reaction of [RhCl(CS)(PPh3)2] with excess catecholborane affords the cumulenic carbido complex [Rh2(μ-C)Cl2(PPh3)4] which undergoes phosphine and halide substitution to afford a range of complexes in which the RhCRh spine remains intact.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02524J
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