Exploring seebeck-coefficient fluctuations in endohedral-fullerene, single-molecule junctions

Author:

Ismael Ali K.12ORCID,Rincón-García Laura3ORCID,Evangeli Charalambos4,Dallas Panagiotis56ORCID,Alotaibi Turki17,Al-Jobory Alaa A.18ORCID,Rubio-Bollinger Gabino39,Porfyrakis Kyriakos610ORCID,Agraït Nicolás3911ORCID,Lambert Colin J.1ORCID

Affiliation:

1. Department of Physics, Lancaster University, Lancaster, UK

2. Department of Physics, College of Education for Pure Science, Tikrit University, Tikrit, Iraq

3. Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid, Spain

4. Department of Materials, University of Oxford, Parks Road, OX1 3PH, Oxford, UK

5. Institute of Nanoscience and Nanotechnology, NCSR Demokritos, 15310 Athens, Greece

6. Department of Materials, University of Oxford, OX1 3PH, UK

7. Department of Physics, College of Science, Jouf University, Sakaka, Saudi Arabia

8. Department of Physics, College of Science, University of Anbar, Anbar, Iraq

9. Condensed Matter Physics Center (IFIMAC) and Instituto Universitario de Ciencia de Materiales “Nicolás Cabrera” (INC), Universidad Autónoma de Madrid, E-28049 Madrid, Spain

10. Faculty of Engineering and Science, University of Greenwich, Central Avenue, Chatham Maritime, ME4 4TB, UK

11. Fundación IMDEA Nanociencia, Calle Faraday 9, Campus Universitario de Cantoblanco, E-28049 Madrid, Spain

Abstract

STM measurements and DFT calculations to study 3 bi-thermoelectric endohedral metallofullerenes, benchmarked against C60, show that the fluctuations in S are correlated with the charge inhomogeneity and the geometrical disorder within the junction.

Funder

Hellenic Foundation for Research and Innovation

Ministry of Higher Education and Scientific Research

Engineering and Physical Sciences Research Council

European Commission

Ministerio de Economía, Industria y Competitividad, Gobierno de España

Comunidad de Madrid

Ministerio de Educación, Cultura y Deporte

Consejería de Educación e Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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