Acetylacetonato-based pincer-type nickel(ii) complexes: synthesis and catalysis in cross-couplings of aryl chlorides with aryl Grignard reagents

Author:

Asano Erika12345,Hatayama Yuki12345,Kurisu Nobutaka12345,Ohtani Atsufumi12345,Hashimoto Toru12345ORCID,Kurihara Youji12345,Ueda Kazuyoshi12345ORCID,Ishihara Shinji6345ORCID,Nagao Hirotaka789105,Yamaguchi Yoshitaka12345ORCID

Affiliation:

1. Department of Advanced Materials Chemistry

2. Graduate School of Engineering

3. Yokohama National University

4. Yokohama 240-8501

5. Japan

6. Instrumental Analysis Center

7. Department of Materials and Life Sciences

8. Faculty of Science and Technology

9. Sophia University

10. Tokyo 102-8554

Abstract

The synthesis of acetylacetoneto-based pincer-type nickel(ii) complexes and their catalytic activity were investigated.

Funder

Japan Society for the Promotion of Science

Kyoto University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference100 articles.

1. Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes

2. Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls

3. Cross-Coupling Reactions: A Practical Guide , ed. N. Miyaura , Springer-Verlag , Berlin, Heidelberg , 2002

4. Metal-Catalyzed Cross-Coupling Reactions , ed. A. de Meijere and F. Diederich , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , 2nd edn, 2004

5. Palladium-Catalyzed Coupling Reactions of Aryl Chlorides

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