Chemisorbed oxygen or surface oxides steer the selectivity in Pd electrocatalytic propene oxidation observed by operando Pd L-edge X-ray absorption spectroscopy

Author:

Koroidov Sergey12345ORCID,Winiwarter Anna61789ORCID,Diaz-Morales Oscar12345ORCID,Görlin Mikaela12345ORCID,Halldin Stenlid Joakim12345ORCID,Wang Hsin-Yi12345ORCID,Börner Mia12345,Goodwin Christopher Matthew12345,Soldemo Markus12345ORCID,Pettersson Lars Gunnar Moody12345,Rossmeisl Jan101112139ORCID,Hansson Tony12345,Chorkendorff Ib61789ORCID,Nilsson Anders12345ORCID

Affiliation:

1. Department of Physics

2. AlbaNova University Center

3. Stockholm University

4. 106 91 Stockholm

5. Sweden

6. SurfCat

7. Technical University of Denmark

8. 2800 Kgs. Lyngby

9. Denmark

10. Nano-Science Center

11. Department of Chemistry

12. University of Copenhagen

13. 2100 Copenhagen

Abstract

Operando Pd X-ray absorption spectroscopy elucidates how the surface oxygen species steer the selectivity in the electrochemical oxidation of propene.

Funder

Vetenskapsrådet

Innovationsfonden

Villum Fonden

Knut och Alice Wallenbergs Stiftelse

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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