Carbon supported hybrid catalysts for controlled product selectivity in the hydrosilylation of alkynes

Author:

Roemer Max12345ORCID,Gonçales Vinicius R.6734ORCID,Keaveney Sinead T.5834ORCID,Pernik Indrek1234ORCID,Lian Jiaxin6734,Downes James9834ORCID,Gooding J. Justin6734ORCID,Messerle Barbara A.58346ORCID

Affiliation:

1. School of Chemistry

2. The University of Sydney

3. Sydney

4. Australia

5. Department of Molecular Sciences

6. School of Chemistry and the Australian Centre for NanoMedicine

7. The University of New South Wales

8. Macquarie University

9. Department of Physics and Astronomy

Abstract

A series of Rh- and Ir-hybrid catalysts with varying tether lengths has been prepared by immobilization of RhI, RhIII and IrIII complexes on carbon black, and applied in the hydrosilylation of alkynes.

Funder

University of Sydney

Macquarie University

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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