Ultrafast structural dynamics in Rydberg excited N,N,N′,N′-tetramethylethylenediamine: conformation dependent electron lone pair interaction and charge delocalization-Reference-Cited by-同舟云学术

Ultrafast structural dynamics in Rydberg excited N,N,N′,N′-tetramethylethylenediamine: conformation dependent electron lone pair interaction and charge delocalization

Published:2014 Issue:11 Volume:5 Page:4394-4403
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Cheng Xinxin¹²³,Zhang Yao¹²³,Deb Sanghamitra¹⁴⁵,Minitti Michael P.⁶⁷⁸,Gao Yan¹²³,Jónsson Hannes¹²³⁹¹⁰,Weber Peter M.¹²³

Affiliation:

1. Department of Chemistry

2. Brown University

3. Providence, USA

4. Duke University

5. Durham, USA

6. Linac Coherent Light Source (LCLS)

7. SLAC National Accelerator Laboratory

8. Menlo Park, USA

9. Faculty of Physical Sciences

10. University of Iceland

Abstract

Time-resolved Rydberg fingerprint spectroscopy and quantum calculations reveal the structure dependent electron lone pair interaction and charge delocalization in real time.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01646G

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5. Photoinduced Electron Transfer Bond Fragmentations

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