Approaching the limit of CuII/CuI mixed valency in a CuIBr2–N-methylquinoxalinium hybrid compound-Reference-Cited by-同舟云学术

Approaching the limit of CuII/CuI mixed valency in a CuIBr2–N-methylquinoxalinium hybrid compound

Published:2015 Issue:64 Volume:51 Page:12740-12743
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Leblanc Nicolas¹²³⁴,Sproules Stephen⁵⁶⁷⁸,Pasquier Claude⁹¹⁰¹¹¹²,Auban-Senzier Pascale⁹¹⁰¹¹¹²,Raffy Helene⁹¹⁰¹¹¹²,Powell Annie K.¹²³⁴¹³

Affiliation:

1. Institut für Nanotechnologie

2. Karlsruher Institut für Technologie

3. D-76344 Eggenstein-Leopoldshafen

4. Germany

5. University of Glasgow

6. School of Chemistry

7. Scotland

8. UK

9. Laboratoire de Physique des Solides

10. UMR-CNRS 8502

11. 91405 Orsay Cedex

12. France

13. Institut für Anorganische Chemie

Abstract

We present a novel 1D hybrid salt (MQ)[CuBr₂]_∞ (MQ = N-methylquinoxalinium) containing less than 0.1% Cu^II and yet shows properties consistent with a mixed valent structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04142B

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